A lot of people in rock and metal will use power chords.. with no minor or major 3rd. So when you've got something like an E5 power chord as the bed of your solo, you can use pretty much any mode you want.
If you had a riff that used E5 and F5, that would give you a good opportunity to use the Phrygian Dominant mode (the Yngwie mode!) because of the interval of E to F..
If you had a chord progression that made use of the E minor scale and then resolved on a B chord or a D#/5+ which is like another inversion of B, then that would be a good place to use the E Harmonic Minor scale.
But neo classical isn't just about the modes, it's about a combination of phrases and chord progressions that overall produce a typically classical sound, bringing to mind those composers like Bach, Paganini etc.. so pedal tone licks are common.
I haven't spent a massive amount of time emulating neo classical so my knowledge is only based on what I hear and have worked out.. some of the theory boffins might be able to direct you better
It would also be interesting hear from my guitar comrades. Fellas, let's help this guy out !
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This post has been edited by Ben Higgins: Dec 4 2013, 07:13 PM